Nonmetal Catalyzed Hydrogenation of Carbonyl Compounds
نویسندگان
چکیده
منابع مشابه
Transition metal-catalyzed reduction of carbonyl compounds
.................................................................................................................... iii List of publications ..................................................................................................... v Abbreviations ............................................................................................................. ix
متن کاملOn the mechanism of carbonyl hydrogenation catalyzed by iron catalyst.
Density functional theory calculations have been performed to investigate the detailed mechanism of the carbonyl hydrogenation catalyzed by the first well-defined bifunctional iron catalyst. The catalytic reaction proceeds by hydrogen transfer and dihydrogen activation. The hydrogen transfer reaction occurs via the bifunctional mechanism in which the two hydrogen atoms attached on the Fe and O ...
متن کاملRecent trends in Pd-catalyzed remote functionalization of carbonyl compounds.
Recent advances in the palladium-catalyzed remote functionalization of carbonyl derivatives are highlighted in this review. The structure of the article is based on the three strategies that have emerged in recent years as the most viable tactics to construct C(sp(3))-C, C(sp(3))-N or C(sp(3))-O bonds at a distance of at least three carbon atoms from the carbonyl functionality. The specific asp...
متن کاملPhosphazene base-catalyzed condensation of trimethylsilylacetate with carbonyl compounds.
The t-Bu-P4 base was found to be an excellent catalyst for the condensation of trimethylsilylacetate or trimethylacetonitrile with carbonyl compounds to form functionalized alkenes and beta-enaminoesters were also synthesized by the condensation with formanilides.
متن کاملHighly enantioselective iridium-catalyzed hydrogenation of heteroaromatic compounds, quinolines.
The highly enantioselective hydrogenation of quinoline derivatives is developed using [Ir(COD)Cl]2/(R)-MeO-Biphep/I2 system, and this methodology has been applied to the asymmetric synthesis of three naturally occurring alkaloids angustureine, galipinine, and cuspareine. This method provided an efficient access to a variety of optically active tetrahydroquinolines with up to 96% ee.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Journal of the American Chemical Society
سال: 2014
ISSN: 0002-7863,1520-5126
DOI: 10.1021/ja5088979